(Institute of Industrial Science, The University of Tokyo) A Japanese research team at The University of Tokyo produced a 3-D cluster molecule based on palladium. First, they created a 'butterfly-shaped' Pd4 framewok, using an organosilicon compounds bearing the aromatic substitutents as both template and support for the palladium atoms. Then, using another template, they connected two butterfly-shaped Pd4 skeleton, via chlorine, into a Pd6 cluster based on edge-sharing tetrahedra. This strategy using organosilicons to design customized subnano-architectures may enable design of a range of functional materials and catalysts.
from EurekAlert! - Technology, Engineering and Computer Science https://ift.tt/2NewwfW
Thursday, February 21, 2019
'Butterfly-shaped' palladium subnano cluster built in 3-D
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